Handbook of GC-MS

Foreword xvii Preface to the Fourth Edition xix 1 Introduction 1 1.1 The Historical Development of the GC-MS Technique 4 References 7 2 Fundamentals 9 2.1 Sample Preparation 9 References 105 2.2 Gas Chromatography 128 References 273 2.3 Mass Spectrometry 291 References 400 3 Evaluation of GC-MS Analyses 413 3.1 Display of Chromatograms 413 3.2 Substance Identification 418 3.3 Quantitation 505 3.4 Frequently Occurring Impurities 523 References 531 4 Applications 541 4.1 Air Analysis According to U.S. EPA Method TO- 14 541 4.2 BTEX in Surface Water as of U.S. EPA Method 8260 549 4.3 Volatile Priority Pollutants 554 4.4 MAGIC 60 - VOC Analysis 560 4.5 irm-GC-MS of Volatile Organic Compounds 569 4.6 Organotin Compounds in Water 572 4.7 Analysis of Dithiocarbamate Pesticides 577 4.8 Pesticides Multi-Method by Single Quadrupole MS 584 4.9 QuEChERSER Analysis of Pesticides 594 4.10 Pesticide Analysis with Ethyl Acetate Extraction and Automated Micro-SPE Clean-up 599 4.11 Multi-Residue Pesticides Analysis in Ayurvedic Churna 603 4.12 Polar Aromatic Amines by SPME 614 4.13 Phthalates in Liquors 619 4.14 Natural Spice Ingredients Capsaicin, Piperine, Thymol, and Cinnamaldehyde 626 4.15 Geosmin and Methylisoborneol in Drinking Water 632 4.16 Flavor and Fragrance Profiling by Dual-Column GC-MS 637 4.17 Aroma Profiling of Cheese 644 4.18 Allergens 649 4.19 Metabolite Profiling 656 4.20 Extractables and Leachables 665 4.21 Volatiles in Car Interiors 677 4.22 Azo Dyes in Leather and Textiles 683 4.23 Fast GC of 16 Priority PAHs 691 4.24 Environmental Contaminants in Fish 697 4.25 Fast GC of PCBs 712 4.26 Dioxin Screening in Food and Feed 718 4.27 Confirmation Analysis of Dioxins and Dioxin-like PCBs 730- 4.28 U.S. EPA 1614 Brominated Flame Retardants PBDEs 739 4.29 PBB Analysis by SPME 747 4.30 THC-A in Urine by NCI 751 4.31 Comprehensive Drug Screening and Quantitation 757 4.32 Drugs of Abuse 762 4.33 Structure Elucidation by CI and MS/MS 766 References 770 Glossary 787 Further Reading 858 Author Index 859 Subject Index 861 Compound Index 881